I think you are more apt to get a chain fire from loose fitting caps on nipples.
Yep, my thoughts exactly.
This grease, or "bore butter", or whatever, over the ball is a somewhat modern invention, with this need most likely being brought about by the many cylinder size variances now found among manufacturers......
The original C&B pistols didn't use anything like that, and the original written instructions for loading the originals never mentioned
anything about OP wads, or grease over the ball.
A simple .002" / .003" oversize ball that is form fitted by shaving lead from the ball while being seated over the powder, along with a "correct" size nipple and cap being used, provides all the "seal" and protection from chain-fires needed for these guns.
I remember reading years ago about tests being conducted by the NMLRA to intentionally create chain-fire conditions, and if I remember correctly, the wrong size cap was most likely the cause of such chain-fires 99.9% of the time.
FWIW;
There is a difference in size between #10 and #11 caps, with the #10 being smaller inside by about .000215 while having a greater inside angle, and they're designed specifically to be used on C&B revolvers.
Most folks use #11 because their rifles use #11's and that's what they have on hand, or they think, or feel the #11 is somehow hotter.
It is
not "hotter" in any way, so don't do that....You're inviting nothing but problems by having a larger or loose fitting cap.
Uncle Russ...