A few thoughts.
First, welcome here, I think you will enjoy your time talking with all the different folks here. It is a good group.
Some things to keep in mind. First, the maximum load the revolver will hold is not necessarily the most accurate. The most fun, maybe, but not the straightest shooting. A good rule of thumb is to start developing an accurate load for it, halve the caliber and start there for powder charge. So, if you have a .36 cal revolver, start at about 18 grains, a .44 caliber start at 22 grains. Use Fffg black powder. If you cannot get it locally, there are a number of places you can order it from. Powder Inc will ship in less than case quantities. I think there might be a few other places that will also.
Keep an eye on what is happening with the revolver as you shoot it. If you happen to see one of the percussion caps has been shaken loose and dropped off due to recoil, stop what you are doing and replace it. No cap on a loaded cylinder is an open door for fire to get into a chamber and ignite a round that you are not intending to shoot. Especially a problem if that chamber happens to line up with the frame of the pistol.
Another thing you will want to do is provide some lubrication. This can be in the form of a pre-lubed wonder wad placed between the powder charge and the ball, or some grease placed over the ball. Some say this will help prevent chain fire, others say is merely keeps fouling soft. The jury is out on that as it's still an ongoing arguement.
Your most accurate load is going to happen when the ball is seated firmly on the powder charge and it is at the mouth of the chamber. For shooting a light powder charge, you are going to need a filler of some sort between the powder and the ball. Corn meal and Creme of Wheat are two things that work well.
More things will come to mind later.