If you ever threw or saw thrown one of those "gag" baseballs with the smaller ball inside a hollow cavity, you get some idea of a possible wobble you might get from a round ball with a good air pocket inside. Not good for the hunter, or the target shooter. Not geeky at all, especially for the guys and gals who hand cast.
LD
Good question SR51!
I would like to respond just a bit to this since I have well over fifty years experience casting bullets and playing around with muzzleloaders.
Dave nailed it...a void, or air space, in a round ball can only be detected by weighing it. And, if it is a large enough void you can see some really silly results down range...curve balls, knuckle balls, drop balls, ya just never know what to expect.
At the same time, I love it!
(It provides the greatest excuses you can imagine, when you do something really stupid.)
Have you ever weighed the round balls from the factory?
Pretty common to find a variance of 2 to 3%.
As far as what the mould says it will throw, and what you actually get, is based on many major manufacturers using the most common alloy from Lyman know as 20:1 (twenty parts pure lead to one part Tin.)
The problem with most folks is their not accepting the fact that plain old wheel weights are as close as you can get to 20:1 without actually mixing the alloy yourself. The BHN of 20:1 is roughly 9, while wheel weights can vary from 9 to 11.
Pure lead will have a BHN of about six nowadays. Many of us old timers can remember when that was 5.5 or maybe a little less!
Personally, I don't get too excited about the hardness...hard can be good in many instances, whereas soft and obturation can be good in other cases.
IMHO, the lowly wheel weight shoots just fine in all my muzzleloaders, albeit roughly .0015 or perhaps .0020 undersize from the same round ball cast with pure lead.
By the same token a pure lead round ball will weigh a wee bit more than the same ball cast from wheel weights.
Of course, the larger the round ball, the more pronounced the weight variance.
I used to fret and whine over every little variance in my muzzleloading, but at my age it just it ain't worth it...not until it reaches a point of greater than 5-6%.
There is, in my opinion, other things that I can put that effort toward that could possibly give me a little better score, assuming i do everything right.
Things such as same Patch thickness, same Patch material, same good Lube, and the same consistent, even, seating pressure without damaging the shape of the ball.
This is just my thoughts on the subject, and like all things in life, everyone's mileage may vary just a wee bit.
Uncle Russ...