i agree - everything seems to be pointing to vent liner. it needs to be internally flush with the barrel and its hole uniformly open. internally that hole can also be coned. remove it, get it filed flush to the barrel wall, open the hole up to 5/64".
it's not the flame that ignites the chamber powder, it's the high temp radiant heat of the pan flash.
there are many parts to the process of loading a flintlock. if one of these steps has issues, so does the ignition sequence, which compromises reliability, there needs to be a clear and open path in the touch hole to allow that super hot air reach in and touch the kernals of 3f in the ante-chamber. that chamber needs to clean and DRY, and compacted with 3f powder that's been indented by the vent picking that was done prior to shooting. the vent hole needs to be open and clear. the frizzen and sharp edge of the flint need to be clean. and so on ......